Towards molecular construction platforms: synthesis of a metallotricyclic spirane based on bis(2,2':6',2"-terpyridine)RuII connectivity.
نویسندگان
چکیده
The design and construction of the first multicomponent stepwise assembly of a -based (tpy=terpyridine), three-dimensional, propeller-shaped trismacrocycle, 8, are reported. Key steps in the synthesis involve the preparation of a hexaterpyridinyl triptycene and its reaction with dimeric, 60°-directional, bisterpyridine-Ru(II) building blocks. Characterization includes ESI- and ESI-TWIM-MS and TEM, along with 1D and 2D (1) H NMR spectroscopy.
منابع مشابه
Ruthenium(II) carbonyl compounds with the 4′-chloro-2,2′:6′,2′′-terpyridine ligand
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ورودعنوان ژورنال:
- Chemistry
دوره 20 36 شماره
صفحات -
تاریخ انتشار 2014